Details

Autor(en) / Beteiligte

• Sun, Dengrong
• Jang, Seungwook
• Yim, Se‐Jun
• Ye, Lin
• Kim, Dong‐Pyo

Titel

Metal Doped Core–Shell Metal‐Organic Frameworks@Covalent Organic Frameworks (MOFs@COFs) Hybrids as a Novel Photocatalytic Platform

Ist Teil von

• Advanced functional materials, 2018-03, Vol.28 (13), p.n/a

Ort / Verlag

Hoboken: Wiley Subscription Services, Inc

Erscheinungsjahr

2018

Link zum Volltext

Quelle

Wiley-Blackwell Journals

Beschreibungen/Notizen

• Metal doped core–shell Metal‐Organic Frameworks@Covalent Organic Frameworks (MOFs@COFs) are presented as a novel platform for photocatalysis. A palladium (Pd) doped MOFs@COFs in the form of Pd/TiATA@LZU1 shows excellent photocatalytic performance for tandem dehydrogenation and hydrogenation reactions in a continuous‐flow microreactor and a batch system, indicating the great potential of the metal doped MOFs@COFs as a multifunctional platform for photocatalysis. Explanations for the performance enhancement are elucidated. An integrated dual‐chamber microreactor coupled with the metal doped MOFs@COFs is introduced to demonstrate a concept of an intensified green photochemical process, which can be broadly extended to challenging liquid–gas tandem and cascade reactions. Pd doped core–shell TiATA@LZU1 is fabricated and shows excellent photocatalytic performance for hydrogenation and dehydrogenation reactions in batch and in a newly designed dual‐chamber microreactor. This indicates a great promise of metal–organic frameworks@covalent organic frameworks (MOFs@COFs) hybrids as a novel platform for efficient photocatalysis.