Details

Autor(en) / Beteiligte

• Ebadi, A.
• Shojaei, S.

Titel

Characterization, crystal structure determination, and luminescent properties of [Pd(4,4′-bit)Cl2]

Ist Teil von

• Journal of structural chemistry, 2017-12, Vol.58 (7), p.1457-1463

Ort / Verlag

Moscow: Pleiades Publishing

Erscheinungsjahr

2017

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Complex [Pd(4,4′-bit)Cl 2 ] ( 1 ) is synthesized by the reaction of PdCl 2 and 4,4′-bithiazole (4,4′-bit) in acetonitrile and crystallized by vapor diffusion of methanol into a dimethyl sulfoxide solution of the complex. This complex is thoroughly characterized by elemental analysis, IR, 1 H NMR, UV-Vis, and luminescence spectroscopy and its structure is studied by the single crystal X-ray diffraction method. The X-ray structure determination shows that in the structure of this complex, the Pd(II) atom is fourcoordinated in a slightly distorted square-planar configuration by two nitrogen atoms from a bidentate 4,4′-bithiazole ligand and two chloride ions.