Details

Autor(en) / Beteiligte

• Novaes, Leandro da Rocha
• de Resende, Neuman Solange
• Salim, Vera Maria Martins
• Secchi, Argimiro Resende

Titel

Modeling, simulation and kinetic parameter estimation for diesel hydrotreating

Ist Teil von

• Fuel (Guildford), 2017-12, Vol.209, p.184-193

Ort / Verlag

Kidlington: Elsevier Ltd

Erscheinungsjahr

2017

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• •Kinetic parameters for HDS and HDN reactions are accurately estimated from experimental data.•Deviations between experimental data and model predictions are below 4% for both reactions.•Statistical results show the good quality of the estimated kinetic parameters.•Intraparticle mass transfer limitation is present in HDS/HDN reactions in commercial catalyst. The modeling and simulation of hydrotreating (HDT) reactors can provide relevant information about optimal operating conditions, reactor design and formulation of catalysts to achieve cleaner fuels. This study developed a phenomenological model to estimate the kinetic parameters for the HDT process using the design of experiments technique. The catalytic tests were carried out in a bench-scale unit with diesel as feedstock under similar conditions to those of the industrial units and commercial nickel-molybdenum on alumina (NiMo/γ-Al2O3) as catalyst. The reactor temperature was varied from 330 to 380°C and liquid hourly space velocity (LHSV) from 0.5 to 1.5h−1, keeping constant hydrogen to oil ratio (H2/oil) and pressure at 800stdm3/m3 and 90bar, respectively. The unknown parameters are estimated from experimental data by minimization of the unweighted least-squares function, using a non-linear optimization method (complex algorithm). The proposed model was able to reproduce different operating conditions with good adjustment and accuracy. Relative deviations below 4% for the experimental data and model prediction were achieved. Statistical parameters, p values, and confidence intervals confirmed the good quality of the estimated kinetic parameters. Internal diffusion resistances were present during hydrodesulfurization (HDS) and hydrodenitrogenation (HDN) reactions. The hydrogen consumption for HDS was higher than for HDN reaction. Finally, the proposed experimental design with 12 catalytic tests was satisfactory to obtain the desired results in a reliable way.