Details

Autor(en) / Beteiligte

• Shen, Xiaobin
• Dai, Jinyue
• Liu, Yuan
• Liu, Xiaoqing
• Zhu, Jin

Titel

Synthesis of high performance polybenzoxazine networks from bio-based furfurylamine: Furan vs benzene ring

Ist Teil von

• Polymer (Guilford), 2017-07, Vol.122, p.258-269

Ort / Verlag

Kidlington: Elsevier Ltd

Erscheinungsjahr

2017

Link zum Volltext

Quelle

Elsevier ScienceDirect Journals Complete

Beschreibungen/Notizen

• A high performance polybenzoxazine derived from bio-based furfurylamine was synthesized in an efficient and straightforward way. For comparison, its petroleum-based analogue was also prepared from 4, 4-diaminodiphenylmethane (DDM). The chemical structures of the precursors were confirmed by Nuclear Magnetic Resonance Spectroscopy (1H-NMR and 13C-NMR) and Fourier Transform Infrared Spectroscopy (FT-IR). After the curing reaction was investigated by Differential Scanning Calorimetry (DSC) and FT-IR in detail, the thermal and mechanical properties of the cured resins were studied by Dynamic Mechanical Analysis (DMA) and Thermogravimetric Analysis (TGA). Results demonstrated that the polybenzoxazine based on furfurylamine (BZ-F) possessed higher glass transition temperature (270 °C) and better thermal stability associated with higher charring ability when compared with the one (BZ-DDM) derived from DDM, which might be attributed to the stronger hydrogen bonding interaction in the BZ-F system and the post-curing reaction on furan ring above 280 °C. In this paper, the hydrogen bonding effect on the properties of polybenzoxazine has been especially studied, which might give us a guidance to design and synthesize the polybenzoxazine with high performance. [Display omitted] •Benzoxazine (BZ-F) with high purity was synthesized from bio-based furfurylamine.•Oxygen atom in furan ring led to more hydrogen bond in pBZ-F system.•pBZ-F system demonstrated higher performance.