Details

Autor(en) / Beteiligte

• Kazheva, O. N.
• Kravchenko, A. V.
• Aleksandrov, G. G.
• Kosenko, I. D.
• Lobanova, I. A.
• Bregadze, V. I.
• Chudak, D. M.
• Buravov, L. I.
• Protasova, S. G.
• Starodub, V. A.
• Dyachenko, O. A.

Titel

Synthesis, structure, and properties of a new bifunctional radical cation salt with ferracarborane anion: (BEDT-TTF)2[8,8´-Cl2-3,3´-Fe(1,2-C2B9H10)2]

Ist Teil von

• Russian chemical bulletin, 2016-09, Vol.65 (9), p.2195-2201

Ort / Verlag

New York: Springer US

Erscheinungsjahr

2016

Link zum Volltext

Quelle

SpringerLink (Online service)

Beschreibungen/Notizen

• A new radical cation salt of bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) with iron(III) bis(1,2-dicarbollide) 8,8´-dichloro derivatives, that is (BEDT-TTF) 2 [8,8´-Cl 2 -3,3´-Fe-(1,2-C 2 B 9 H 10 ) 2 ], was synthesized. Its electroconducting and magnetic characteristics were studied, molecular and crystal structures were determined. The electroconductivity of crystals at room temperature was σ 293 ~5 Ω –1 cm –1 , which is close to the corresponding value for the salt of cobalt bis(1,2-dicarbollide) dichloro derivative and is considerably higher than the electroconductivity of a similar salt of unsubstituted iron bis(1,2-dicarbollide). The measurements of magnetic susceptibility at 2—300 K showed that this salt is paramagnetic.