Details

Autor(en) / Beteiligte

• Czylkowska, A.
• Raducka, A.
• Mierczyński, P.

Titel

Synthesis, thermal study and some properties of Zn(II), Cd(II) and Pb(II) compounds with mono-, di- and trichloroacetates

Ist Teil von

• Journal of thermal analysis and calorimetry, 2017-05, Vol.128 (2), p.937-946

Ort / Verlag

Dordrecht: Springer Netherlands

Erscheinungsjahr

2017

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• New complexes with formulae: Zn(CClH 2 COO) 2 ·2H 2 O, Zn(CCl 2 HCOO) 2 ·2H 2 O, Zn(CCl 3 COO) 2 ·2H 2 O, Cd(CCl 2 HCOO) 2 ·H 2 O, Cd(CCl 3 COO) 2 ·2H 2 O and Pb(CCl 3 COO) 2 ·2H 2 O, were prepared and characterized by chemical, elemental analysis and IR spectroscopy. The nature of metal–ligand coordination was studied. They are small crystalline. The thermal properties of compounds in the solid state were studied using TG–DTG techniques under dynamic flowing air atmosphere. Mass spectrometer was used to analyze principal volatile thermal decomposition and fragmentation products of Zn(CCl 3 COO) 2 ·2H 2 O evolved during pyrolysis in dynamic flowing air and in argon atmosphere.