Details

Autor(en) / Beteiligte

• Shkerin, S. N.
• Uporov, S. A.
• Yudin, V. N.
• Solodovnikov, S. F.
• Zolotova, E. S.
• Tolkacheva, A. S.

Titel

Paramagnetic properties of triple molybdates CsNa5M3(MoO4)6 (M = Ni, Co, Mn)

Ist Teil von

• Russian Journal of Physical Chemistry A, 2016-11, Vol.90 (11), p.2292-2296

Ort / Verlag

Moscow: Pleiades Publishing

Erscheinungsjahr

2016

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The static magnetization of CsNa 5 M 3 (MoO 4 ) 6 single phase molybdates, where M = Co, Ni, and Mn, is measured at 4–300 K in magnetic fields of up to 20 kOe. It is shown that the materials are paramagnetic. Magnetization as a function of temperature is described using the Curie–Weiss law. The intrinsic magnetic moments of the phases are found to be 9.759 (Co), 6.958 (Ni), and 12.203 Bohr magnetons for manganese molybdates. It is concluded that the charge state of Co, Ni, and Mn cations in the compounds is +2.