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A 28 keV beam of
31
Mg
+
ions was extracted from a uranium carbide, proton-beam-irradiated target coupled to a laser ion source. The ion beam was nuclear-spin polarized by collinear optical pumping on the
2
S
1
/
2
–
2
P
1
/
2
transition at 280 nm. The polarization was preserved by an extended 1 mT guide field as the beam was transported via electrostatic bends into a 2.5 T longitudinal magnetic field. There the beam was implanted into a single crystal MgO target and the beta decay asymmetry was measured. Both hyperfine ground states were optically pumped with a single frequency light source, using segmentation of the beam energy, which boosted the polarization by approximately 50 % compared to pumping a single ground state. The total decay asymmetry of 0.06 and beam intensity were sufficient to provide a useful spin-1/2 beam for future BNMR experiments. A variant of the method was used previously to optically pump the full Doppler-broadened absorption profile of a beam of
11
Be
+
with a single-frequency light source.