Details

Autor(en) / Beteiligte

• Ganesan, S.
• Karthika, P.
• Rajarathinam, R.
• Arthanareeswari, M.
• Mathew, Vinod
• Maruthamuthu, P.

Titel

A poly (ethylene oxide), poly (vinylidene fluoride) and polycapro lactone polymer blend doped with an indigenous nitrogen–sulfur based organic compound as a novel electrolyte system for dye-sensitized solar cell applications

Ist Teil von

• Solar energy, 2016-10, Vol.135, p.84-91

Ort / Verlag

New York: Elsevier Ltd

Erscheinungsjahr

2016

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• •Introduction of PCL in PEO and PVdF along with KI, I2 and 2, 6-bis (2-thio pyridyl) pyridine in the polymer blend electrolyte is novel method.•The synthesis of compound 2, 6-bis (2-thio pyridyl) pyridine and the preparation of polymer blend electrolyte is cost-effective method.•The enhanced conductivity of BTPP doped PEO–PVdF–PCL based polymer electrolyte of 9.5×10−4Scm−1.•The fabricated solar cell exhibited efficiency as high as 9.3% for BTPP doped PEO based polymer blend electrolyte.•This is comparatively higher than those of the present day DSSCs fabricated with poly (ethylene oxide) polymer electrolyte. The present study reports, for the first time, the strategy of blending three different polymers followed by the doping of an organic nitrogenous compound to develop a solvent-free novel doped multi-polymer blend electrolyte system for dye-sensitized solar cell (DSSC) applications. Precisely, this novel electrolyte consists of poly (ethylene oxide) (PEO) blended with poly (vinylidene fluoride) (PVdF) and poly (capro lactone) (PCL) that is incorporated into the synthesized 2,6-bis (2-thio pyridyl) pyridine (BTPP) along with KI and I2. The current–voltage (I–V) characteristics of the nanocrystalline DSSC fabricated using the present electrolyte generates a photocurrent of 15.5mA/cm2, a photo-voltage of 905mV, a fill factor of 0.53 and yields an overall energy conversion efficiency of 9.3% under a simulated sunlight radiation of 80mW/cm2. The impressive photoelectric performance of the fabricated solar cell is mainly attributed to the synergic effects of the electrolyte composed of the unique blending of three polymers and the electron donicity of BTPP that leads to strongly influence the interaction between the nanocrystalline TiO2 electrode and I−/I3− electrolyte, thereby leading to high conversion efficiency.