Details

Autor(en) / Beteiligte

• Dong, Wei-Li
• Cai, Wen-Xi
• Wu, Rui
• Li, Zheng-Ming
• Zhao, Wei-Guang
• Liu, Xing-Hai

Titel

A convenient method for reduction dehalogenation of [alpha]-halocarbonyl compounds using benzenethiol in K+/CH3CN system

Ist Teil von

• Phosphorus, sulfur, and silicon and the related elements, 2016-07, Vol.191 (7), p.980

Ort / Verlag

Abingdon: Taylor & Francis Ltd

Erscheinungsjahr

2016

Quelle

Taylor & Francis

Beschreibungen/Notizen

• Benzenethiol, as a reductive agent for the dehalogenation of various α-halocarbonyl compounds, is investigated in the K+/CH3CN system. The reaction affords the reduced compounds in high yields under mild reaction conditions, especially α-chlorocarbonyl compounds. Furthermore, the reaction performed under ultrasonic irradiation greatly shortens the reaction time.