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Preparation of La/Co/Ni-based anode catalyst for biogas-fueled solid oxide fuel cells
Ist Teil von
Journal of electroceramics, 2015-12, Vol.35 (1-4), p.75-80
Ort / Verlag
New York: Springer US
Erscheinungsjahr
2015
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
A new type of bilayered-anode for application in biogas-fueled solid oxide fuel cells (SOFCs) was investigated. The bilayered-anode consisted of lanthanum- and cobalt-doped nickel oxide mixed with Sc
2
O
3
-stabilized ZrO
2
electrolyte material (LaCoNi-ScSZ) as a functional catalyst layer mainly for the reforming reaction and NiO-ScSZ as an active anode layer mainly for the electrochemical reaction. The cell performance was characterized by recording
I
-
V
curves and impedance spectra. The SOFC featuring the LaCoNi-ScSZ functional catalyst anode layer exhibited a power density of 0.32 W/cm
2
when operated under a humidified synthetic biogas (60 % CH
4
and 40 % CO
2
) at 700 °C. The presence of LaCoNi-ScSZ functional catalyst afforded a high coking resistance, and thus the cell was stable when operated under the synthetic biogas at 700 °C for 45 h.