Sie befinden Sich nicht im Netzwerk der Universität Paderborn. Der Zugriff auf elektronische Ressourcen ist gegebenenfalls nur via VPN oder Shibboleth (DFN-AAI) möglich. mehr Informationen...
Novel [lambda]3-Iodane-Based Functionalization of Synthetic Carbon Allotropes (SCAs)--Common Concepts and Quantification of the Degree of Addition
Ist Teil von
Chemistry : a European journal, 2014-12, Vol.20 (50), p.16644
Ort / Verlag
Weinheim: Wiley Subscription Services, Inc
Erscheinungsjahr
2014
Quelle
Wiley Online Library - AutoHoldings Journals
Beschreibungen/Notizen
The covalent functionalization of carbon allotropes represents a main topic in the growing field of nano materials. However, the development of functional architectures is impeded by the intrinsic polydispersibility of the respective starting material, the unequivocal characterization of the introduced functional moieties, and the exact determination of the degree of functionalization. Based on a novel carbon allotrope functionalization reaction, utilizing λ3-iodanes as radical precursor systems, we were able to demonstrate the feasibility to separate and to quantify thermally detached functional groups, formerly covalently linked to carbon nanotubes and graphene through thermogravimetric GC-MS.