Details

Autor(en) / Beteiligte

• Fan, Le-Qing
• Wu, Ji-Huai
• Huang, Yun-Fang

Titel

Two 2D 3d-4f Heterometallic Coordination Polymers with [Ln2(IN)6(OH)]- Clusters and [Cu4Br3]nn+ Chains

Ist Teil von

• Zeitschrift für anorganische und allgemeine Chemie (1950), 2014-06, Vol.640 (7), p.1462-1466

Ort / Verlag

Weinheim: WILEY-VCH Verlag

Erscheinungsjahr

2014

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Two 2D 3d‐4f heterometallic coordination polymers, [Ln2Cu4Br3(IN)6(OH)(H2O)4]n [Ln = Ho (1) and Yb (2), HIN = isonicotinic acid], were synthesized by hydrothermal reaction of Ln2O3, CuBr2, and HIN with HNO3, and characterized by elemental analyses, IR spectroscopy, PXRD, and single‐crystal X‐ray diffraction. Structural analyses revealed that 1 and 2 are isostructural and have a 2D structure, which consists [Cu4Br3]nn+ chains linked by dinuclear [Ln2(IN)6(OH)]– clusters. Additionally, the thermogravimetric analysis and luminescent properties of 1 were investigated and discussed.