Details

Autor(en) / Beteiligte

• Tejel, Cristina
• Asensio, Laura
• del Río, M. Pilar
• de Bruin, Bas
• López, José A.
• Ciriano, Miguel A.

Titel

Developing Synthetic Approaches with Non-Innocent Metalloligands: Easy Access to IrI/Pd0 and IrI/Pd0/IrI Cores

Ist Teil von

• Angewandte Chemie (International ed.), 2011-09, Vol.50 (38), p.8839-8843

Auflage

International ed. in English

Ort / Verlag

Weinheim: WILEY-VCH Verlag

Erscheinungsjahr

2011

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Guilty as charged is the verdict for anionic Ir complex [Ir(bpa−2 H)(cod)]− in its reactions with PdII compounds. The net transfer of two electrons from the Ir complex to Pd allows easy preparation of di‐ and trinuclear π‐imine‐coordinated Pd0 compounds such as [{Ir(PyCH2NCHPy)(cod)}2Pd] (see picture; C white, Ir red, N blue, Pd yellow). bpa−2 H: doubly deprotonated form of N,N‐bis(2‐picolyl)amine (bpa); cod: 1,5‐cyclooctadiene.