Details

Autor(en) / Beteiligte

• Bartyzel, Agata

Titel

Synthesis, crystal structure and characterization of manganese(III) complex containing a tetradentate Schiff base

Ist Teil von

• Journal of coordination chemistry, 2013-12, Vol.66 (24), p.4292-4303

Ort / Verlag

Abingdon: Taylor & Francis

Erscheinungsjahr

2013

Quelle

Taylor & Francis Journals Auto-Holdings Collection

Beschreibungen/Notizen

• N,N′-bis((2-hydroxyphenyl)(phenyl)methylidene)propane-1,2-diaminato-N,N′,O,O′)-(nitrato-O)-manganese(III) methanol solvate ([Mn(C 29 H 24 N 2 O 2 )(NO 3 )CH 3 OH]) was synthesized and characterized by FTIR, UV-Vis, TG-FTIR, TG/DSC, molar conductivity, magnetic moment measurement and single crystal X-ray analysis. In the structure, the Mn(III) ion adopts a distorted octahedral geometry with two nitrogen and two oxygen atoms from the Schiff base ligand in the equatorial plane, and the nitrate ion and methanol molecule in the axial position. The effects of organic solvents of various polarities on the UV-Vis spectra of the ligand and complex were investigated. The manganese(III) complex is easily dissolved in organic polar aprotic solvents and has moderate solubility in organic polar protic solvents.