Details

Autor(en) / Beteiligte

• Huang, Yu-Lun
• Lu, Duan-Yen
• Yu, Hsien-Cheng
• Yu, Jen-Shiang K
• Hsu, Chia-Wei
• Kuo, Ting-Shen
• Lee, Gene-Hsiang
• Wang, Yu
• Tsai, Yi-Chou

Titel

Stepwise Construction of the CrCr Quintuple Bond and Its Destruction upon Axial Coordination

Ist Teil von

• Angewandte Chemie International Edition, 2012-07, Vol.51 (31), p.7781

Auflage

International ed. in English

Ort / Verlag

Weinheim: Wiley Subscription Services, Inc

Erscheinungsjahr

2012

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Give me five! Terdentate 2,6-diamidopyridyl ligands were used to stabilize the Cr-Cr quintuple bond and have made it possible to isolate and characterize not only the Cr-Cr quintuple-bonded complex, but also the mixed-valent intermediates (Cr(I) and Cr(II)), which are important species in the formation of typeI quintuple-bonded complexes.