Details

Autor(en) / Beteiligte

• Li, Wen-Ge
• Zhang, You-Cai
• Wang, Zuo-Wei
• Li, Yi-Zhi
• Zheng, He-Gen

Titel

Bis(2,2′-bipyridine)iodo­(oxo)tri-μ3-sulfido-tricopper(I)tungsten(VI)

Ist Teil von

• Acta crystallographica. Section C, Crystal structure communications, 2006-04, Vol.62 (4), p.m159-m160

Ort / Verlag

5 Abbey Square, Chester, Cheshire CH1 2HU, England: Blackwell Publishing Ltd

Erscheinungsjahr

2006

Link zum Volltext

Quelle

Wiley Online Library Journals Frontfile Complete

Beschreibungen/Notizen

• The title nest‐shaped cluster, [Cu3WIOS3(C10H8N2)2], has been synthesized by the reaction of (NH4)2[WOS3], CuI and 2,2′‐bipyridine (bipy) in dimethyl­formamide under a purified nitro­gen atmosphere. The cluster has a neutral skeleton containing the bipy ligands, and the central W atom is tetra­hedrally coordinated by three S atoms and one O atom. The three Cu atoms are divided into two different kinds. Two Cu atoms adopt distorted tetra­hedral geometry, with each Cu atom coordinated by two S atoms and the two N atoms of a bipy ligand. The other Cu atom adopts a trigonal mode surrounded by two S atoms and one I atom.