Details

Autor(en) / Beteiligte

• Grier, Elizabeth J.
• Petford-Long, Amanda K.
• Ward, Roger C. C.

Titel

Determination of hydrogen ordering within the β-RH2+x phase (R = Ho, Y) using electron diffraction techniques

Ist Teil von

• Journal of applied crystallography, 2000-10, Vol.33 (5), p.1246-1252

Ort / Verlag

5 Abbey Square, Chester, Cheshire CH1 2HU, England: Munksgaard International Publishers

Erscheinungsjahr

2000

Quelle

Wiley-Blackwell Journals

Beschreibungen/Notizen

• Computer simulations of the electron diffraction patterns along the [10] zone axes of four ordered structures within the β‐RH2+x phase, with R = Ho or Y, and 0 ≤x≤ 0.25, have been performed to establish whether or not the hydrogen ordering could be detected using electron diffraction techniques. Ordered structures within other RH2+x (R = Ce, Tb) systems have been characterized with neutron scattering experiments; however, for HoH(D)2+x, neutron scattering failed to characterize the superstructure, possibly because of the low x concentration or lack of long‐range order within the crystal. This paper aims to show that electron diffraction could overcome both of these problems. The structures considered were the stoichiometric face‐centred cubic (f.c.c.) fluorite structure (x = 0), the D1 structure (x = 0.125), the D1a structure (x = 0.2) and the D022 structure (x = 0.25). In the stoichiometric structure, with all hydrogen atoms located on the tetrahedral (t) sites, only the diffraction pattern from the f.c.c. metal lattice was seen; however, for the superstoichiometric structures, with the excess hydrogen atoms ordered on the octahedral (o) sites, extra reflections were visible. All the superstoichiometric structures showed extra reflections at the (001)f.c.c. and (110)f.c.c. type positions, with structure D1 also showing extra peaks at (½ ½ ½)f.c.c.. These reflections are not seen in the simulations at similar hydrogen concentrations with the hydrogen atoms randomly occupying the o vacancies.