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In an experiment at the Recoil Mass Spectrometer at the Holifield Radioactive Ion Beam Facility, the very small a-decay branch of 109I, ba=(1.4+/-0.4)?10-4, has been measured. The Qavalue for this transition allowed for the determination of Q,(105Sb)=356+/-22 keV, about 130 keV lower than previously claimed. This difference increases the partial half-life for proton decay by several orders of magnitude, making the probability of observing direct proton decay of 105Sb very small, much below any previous experimental limit. The results and consequences for the astrophysical rp-process are discussed.