Industrial & engineering chemistry research, 1994-03, Vol.33 (3), p.488-492
1994
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Details
- Autor(en) / Beteiligte
- Titel
- Promoting Effect of Tin on Ni/C Catalyst for Methanol Carbonylation
- Ist Teil von
- Industrial & engineering chemistry research, 1994-03, Vol.33 (3), p.488-492
- Ort / Verlag
- Washington, DC: American Chemical Society
- Erscheinungsjahr
- 1994
- Quelle
- Alma/SFX Local Collection
- Beschreibungen/Notizen
- Vapor-phase carbonylation of methanol was investigated under atmospheric pressure on Ni/C and Sn-Ni/C catalysts. Sn-Ni/C was found as having a significantly higher activity than Ni/C in converting methanol and CO to methyl acetate and acetic acid. Product distributions of the two catalysts did not markedly differ from each other. Characterizing the catalysts by XRD demonstrated that Ni[sub 3]Sn had formed on Sn-Ni/C. The adsorption of CO became substantially enhanced by the addition of Sn to Ni/C. This addition also resulted in a slightly higher CO adsorption strength.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 0888-5885eISSN: 1520-5045DOI: 10.1021/ie00027a003Titel-ID: cdi_osti_scitechconnect_7275628
- Format
- –
- Schlagworte
- 10 SYNTHETIC FUELS, 100300 - Synthetic Fuels- Properties & Composition- (1990-), ACTIVATED CARBON, ADSORBENTS, ALCOHOLS, Applied sciences, CARBON, CARBON COMPOUNDS, CARBON MONOXIDE, CARBON OXIDES, CARBONYLATION, CATALYST SUPPORTS, CATALYTIC EFFECTS, CHALCOGENIDES, Chemical industry and chemicals, CHEMICAL REACTIONS, CHEMISORPTION, ELEMENTS, Exact sciences and technology, HYDROXY COMPOUNDS, Industrial chemicals, METALS, METHANOL, NICKEL, NONMETALS, ORGANIC COMPOUNDS, Organic industry, OXIDES, OXYGEN COMPOUNDS, PROMOTERS, SEPARATION PROCESSES, SORPTION, TIN, TRANSITION ELEMENTS