Journal of the American Chemical Society, 1989-07, Vol.111 (14), p.5502-5504
1989
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Details
- Autor(en) / Beteiligte
- Titel
- Reductive elimination of methane from a cationic rhenium methyl hydride. Evidence for an intermediate methane complex
- Ist Teil von
- Journal of the American Chemical Society, 1989-07, Vol.111 (14), p.5502-5504
- Ort / Verlag
- Washington, DC: American Chemical Society
- Erscheinungsjahr
- 1989
- Quelle
- Alma/SFX Local Collection
- Beschreibungen/Notizen
- Although intramolecular agostic interactions between transition-metal centers and pendant C-H bonds are well-characterized, there is less evidence for the coordination of free hydrocarbon C-H bonds to transition-metal moieties. Such complexes of alkanes are of great importance due to the intense current interst in homogeneous alkane activation reactions. The authors present evidence for an intermediate methane complex in the reductive elimination of methane from a rhenium methyl hydride.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 0002-7863eISSN: 1520-5126DOI: 10.1021/ja00196a087Titel-ID: cdi_osti_scitechconnect_6708722
- Format
- –
- Schlagworte
- 360104 -- Metals & Alloys-- Physical Properties, ALKANES, CALCULATION METHODS, CHEMICAL BONDS, CHEMICAL REACTIONS, Chemistry, DATA, DATA ANALYSIS, Exact sciences and technology, EXPERIMENTAL DATA, HYDRIDES, HYDROCARBONS, HYDROGEN COMPOUNDS, INFORMATION, INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY, Kinetics and mechanisms, MATERIALS SCIENCE, MEASURING INSTRUMENTS, MEASURING METHODS, METHANE, NUMERICAL DATA, Organic chemistry, ORGANIC COMPOUNDS, Reactivity and mechanisms, REFRACTORY METAL COMPOUNDS, RHENIUM COMPOUNDS, RHENIUM HYDRIDES, TRANSITION ELEMENT COMPOUNDS 400200 -- Inorganic, Organic, & Physical Chemistry