Details

Autor(en) / Beteiligte

• Conradson, Steven D.
• Raistrick, Ian D.
• Bishop, Alan R.

Titel

Axial Oxygen-Centered Lattice Instabilities and High-Temperature Superconductivity

Ist Teil von

• Science (American Association for the Advancement of Science), 1990-06, Vol.248 (4961), p.1394-1398

Ort / Verlag

Washington, DC: American Society for the Advancement of Science

Erscheinungsjahr

1990

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Copper K-edge x-ray absorption data indicate that an axial oxygen-centered lattice instability accompanying the 93 K superconducting transition in YBa$_2$Cu$_3$O$_7$ is of a pseudo-(anti)ferroelectric type, in that it appears to involve the softening of a double potential well into a structure in which the difference between the two copper-oxygen distances and the barrier height have both decreased. This softer structure is present only at temperatures within a fluctuation region around the transition. A similar process involving the analogous axial oxygen atom also accompanies the superconducting transition in TIBa$_2$Ca$_3$Cu$_4$O$_11$, where the superconducting transition temperature T$_c$ is ∼-120 K The mean square relative displacement of this oxygen atom in YBa$_2$Cu$_3$O$_7$ is also specifically affected by a reduction in the oxygen content and by the substitution of cobalt for copper, providing further evidence for the sensitivity of the displacement to additional factors that also influence the superconductivity. On the basis of the implied coupling of this ionic motion to the superconductivity, a scenario for high-temperature superconductivity is presented in which both phonon and electronic (charge transfer) channels are synergistically involved