Details

Autor(en) / Beteiligte

• Lu, J. F.
• Tang, Z. H.
• Shi, J.
• Ge, H. G.
• Jiang, M.
• Song, J.
• Jin, L. X.

Titel

A Novel Coordination Polymer Based on Trinuclear Cobalt Building Blocks Cluster: Synthesis, Crystal Structure, and Properties

Ist Teil von

• Crystallography reports, 2017-12, Vol.62 (7), p.1041-1045

Ort / Verlag

Moscow: Pleiades Publishing

Erscheinungsjahr

2017

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The title compound {[Co 3 (μ 3 -OH)(μ 2 -H 2 O)2(H 2 O) 5 (BTC) 2 ] · 6H 2 O} n (H 3 BTC is a 1,3,5-benzenetricarboxylic acid) was prepared and characterized by single crystal and powder X-ray diffraction, Fourier transform infrared spectroscopy, thermogravimetric and elemental analyses. The single crystal X-ray diffraction reveals that the title compound consists of 1D infinite zigzag chains which were constructed by trinuclear cobalt cluster and BTC 3– ligand. Neighbouring above-mentioned 1D infinite zigzag chains are further linked by intermolecular hydrogen bonding to form a 3D supermolecular structure. In addition, the luminescent properties of the title compound were investigated.