Details

Autor(en) / Beteiligte

• Kumar, Sandeep
• Andotra, Savit
• Kaur, Mandeep
• Gupta, Vivek K.
• Kant, Rajni
• Pandey, Sushil K.

Titel

Synthesis, characterization and single crystal x-ray analysis of a complex of iron(II) bis(2,4-dimethylphenyl)dithiophosphate with 4-ethylpyridine

Ist Teil von

• Crystallography reports, 2016-09, Vol.61 (5), p.810-814

Ort / Verlag

Moscow: Pleiades Publishing

Erscheinungsjahr

2016

Quelle

SpringerLink

Beschreibungen/Notizen

• Complex of iron(II) bis(2,4-dimethylphenyl)dithiophosphate with 4-ethylpyridine [{(2,4- (CH 3 ) 2 C 6 H 3 O)2PS2}2Fe{NC 5 H 4 (C 2 H 5 )-4} 2 ] is synthesized and characterized by elemental analysis, magnetic moment, IR spectroscopy and single crystal X-ray analysis. Complex crystallizes in the monoclinic sp. gr. P 2 1 / n , Z = 2. Crystal structure consists of mononuclear units with Fe(II) ion chelated by four S atoms of the two diphenyldithiophosphate ligands in bidentate manner. N atoms from two 4-ethylpyridine ligands are axially coordinated to the Fe(II) atom leading to an octahedral geometry.