Details

Autor(en) / Beteiligte

• Feng, Yefeng
• Gong, Honghong
• Xie, Yunchuan
• Wei, Xiaoyong
• Yang, Lanjun
• Zhang, Zhicheng

Titel

Strong induced polarity between Poly(vinylidene fluoride-co-chlorotrifluoroethylene) and α-SiC and its influence on dielectric permittivity and loss of their composites

Ist Teil von

• Journal of applied physics, 2015-03, Vol.117 (9)

Ort / Verlag

Melville: American Institute of Physics

Erscheinungsjahr

2015

Quelle

AIP Journals Complete

Beschreibungen/Notizen

• Interface polarization and interface zone have been widely utilized to account for the abnormally improved dielectric properties of composites although their formation is rather vague and their influence has never been directly measured. In this work, micro α-SiC was designed as the filler particles incorporated into poly(vinylidenefluoride-co-chlorotrifluoroethylene) with internal double bonds (P(VDF-CTFE-DB)) to construct polymer micro composites through solution casting method. The dielectric constant of the composites is found to be increasing linearly as SiC content increases at lower content and the highest value is obtained as 83 at 100 Hz, which is unusually higher than both pristine polymer (13@100 Hz) and SiC filler (17@100 Hz). By studying the dielectric properties of a bilayer model composite, the real dielectric permittivity of SiC sheet and P(VDF-CTFE-DB) layer has been directly measured to be significantly enhanced than their original value. The induced polarity between high polar PVDF units in polymer matrix and the electron-hole dipoles in α-SiC is responsible for the elevated dielectric properties of both components, which could address the failure of binary series and parallel models in predicting the dielectric permittivity of 0-3 composites as well. The strong dependence of induced polarity on the volume content, thickness, and polar nature of both components strongly suggests establishing promising high induced polarity between polymer matrix and fillers may provide an alternative strategy for fabricating high-k composites.