Details

Autor(en) / Beteiligte

• Luo, Langli
• Kang, Yihong
• Yang, Judith C.
• Su, Dong
• Stach, Eric A.
• Zhou, Guangwen

Titel

Comparative study of the alloying effect on the initial oxidation of Cu-Au(100) and Cu-Pt(100)

Ist Teil von

• Applied physics letters, 2014-03, Vol.104 (12)

Ort / Verlag

Melville: American Institute of Physics

Erscheinungsjahr

2014

Quelle

American Institute of Physics

Beschreibungen/Notizen

• Using in situ transmission electron microscopy, we show that the oxidation of the Cu-Au(100) results in the formation of Cu2O islands that deeply embed into the Cu-Au substrate while the oxidation of the Cu-Pt(100) leads to the formation of Cu2O islands that highly protrude above the Cu-Pt substrate. Their difference is attributed to the different mobilities of Pt and Au in the Cu base alloys for which the sluggish mobility of Pt in Cu results in trapped Pt atoms at the oxide/alloy interface while the faster mobility of Au in Cu leads to enhanced rehomogenization of the alloy composition.