Details

Autor(en) / Beteiligte

• Xu, H.
• Zhao, Y.
• Vogel, S.C.
• Daemen, L.L.
• Hickmott, D.D.

Titel

Anisotropic thermal expansion and hydrogen bonding behavior of portlandite: A high-temperature neutron diffraction study

Ist Teil von

• Journal of solid state chemistry, 2007-04, Vol.180 (4), p.1519-1525

Ort / Verlag

San Diego, CA: Elsevier Inc

Erscheinungsjahr

2007

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The structure of deuterated portlandite, Ca(OD) 2, was investigated using time-of-flight neutron diffraction in the temperature range 308–643 K. Rietveld analysis reveals that with increasing temperature, the c dimension expands at a rate ∼4.5 times larger than that for a. This anisotropy of thermal expansion is due to rapid increase in the interlayer thickness along c with increasing temperature. Fitting of the measured cell volumes yields a coefficient of thermal expansion, α= α 0+ α 1 T, where α 0=5.966×10 −5 K −1 and α 1=3.333×10 −8 K −2. On heating, hydrogen-mediated interatomic interactions within the interlayer become weakened, as reflected by increases in the interlayer D⋯O and D⋯D distances with increasing temperature. Correspondingly, the three equivalent sites over which D is disordered become further apart, suggesting a more delocalized configuration of D at high temperatures. With increasing temperature, the Ca(OD) 2 structure expands ∼4.5 times larger between the [CaO 6] octahedral layers than within the layers. Correspondingly, the D-mediated interatomic interactions become significantly weakened, and the three equivalent sites over which D is disordered become further apart, suggesting a more delocalized configuration of D at elevated temperatures.