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Thermal quenching of cathodoluminescence from ZnS:Ag,Cl powder phosphors
Ist Teil von
Journal of applied physics, 2005-02, Vol.97 (3), p.033521-033521-4
Ort / Verlag
United States: American Institute of Physics
Erscheinungsjahr
2005
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
Thermal quenching of cathodoluminescence (CL) was studied by incrementally increasing the temperature of a ZnS:Ag,Cl phosphor without exposure to a continuous electron beam and measuring the decreased CL intensity. A characteristic thermal quenching temperature of 150°C with an activation energy
(
E
a
)
of 0.87 eV was measured. In addition to the reduced CL intensity, the spectra shifted to longer wavelengths and changed shape at elevated temperature due to band gap narrowing at high temperatures and to copper contamination from the heater stage. The CL spectral distribution and intensity were 100% recoverable upon cooling back to room temperature when the electron beam exposure was
<
1
C
∕
cm
2
.