Details

Autor(en) / Beteiligte

• Liu, Yilang
• McGill, Charles J.
• Green, William H.
• Deshlahra, Prashant

Titel

Effects of surface species and homogeneous reactions on rates and selectivity in ethane oxidation on oxide catalysts

Ist Teil von

• AIChE journal, 2021-10, Vol.67 (12)

Ort / Verlag

United States: American Institute of Chemical Engineers

Erscheinungsjahr

2021

Quelle

Wiley Online Library

Beschreibungen/Notizen

• Abstract Selective alkane oxidations on metal oxide catalysts involve complex mechanisms with multiple reactions in series and parallel, different types of reduced and oxidized surface species, and potential contributions from gas‐phase reactions. Here, kinetics and thermodynamics of elementary steps involved in C 2 H 6 ‐O 2 reactions on SiO 2 ‐supported small vanadium oxide domains are determined using density functional theory. These surface reactions together with gas‐phase mechanisms are incorporated in kinetic simulations to determine how surface and gaseous reactions interact and contribute to rates and selectivity. The results show that gas‐phase reactions within pore volumes in contact with the catalyst contribute significantly to C 2 H 6 activation rates, even at conditions where gas‐phase reactions in empty volumes without catalyst are negligible. The majority of C 2 H 6 activations occur on the surface, via H abstraction by vanadium oxo species present at terminal lattice oxygens. The gas‐phase activations via H‐abstraction by OH radicals also exhibit significant contributions. The reduced centers formed by reactions at vanadium oxo species are re‐oxidized rapidly and, therefore, are present in very small concentrations at reaction conditions. The re‐oxidation steps lead to the formation of HO 2 radicals and surface peroxo species that are also rapidly consumed and are present in small concentrations. The peroxo species preferentially convert C 2 H 4 to its epoxide product and influence selectivity even at low concentrations. The gas‐phase reactions decrease the concentrations of peroxo species and improve selectivity slightly. The effects of reaction conditions and catalyst site density provide further insights into how factors beyond conversions at lattice oxygens influence rates and selectivity in alkane oxidation reactions of significant industrial importance.