Details

Autor(en) / Beteiligte

• Han, Lili
• Cheng, Hao
• Liu, Wei
• Li, Haoqiang
• Ou, Pengfei
• Lin, Ruoqian
• Wang, Hsiao-Tsu
• Pao, Chih-Wen
• Head, Ashley R.
• Wang, Chia-Hsin
• Tong, Xiao
• Sun, Cheng-Jun
• Pong, Way-Faung
• Luo, Jun
• Zheng, Jin-Cheng
• Xin, Huolin L.

Titel

A single-atom library for guided monometallic and concentration-complex multimetallic designs

Ist Teil von

• Nature materials, 2022-06, Vol.21 (6), p.681-688

Ort / Verlag

London: Nature Publishing Group UK

Erscheinungsjahr

2022

Quelle

Nature

Beschreibungen/Notizen

• Atomically dispersed single-atom catalysts have the potential to bridge heterogeneous and homogeneous catalysis. Dozens of single-atom catalysts have been developed, and they exhibit notable catalytic activity and selectivity that are not achievable on metal surfaces. Although promising, there is limited knowledge about the boundaries for the monometallic single-atom phase space, not to mention multimetallic phase spaces. Here, single-atom catalysts based on 37 monometallic elements are synthesized using a dissolution-and-carbonization method, characterized and analysed to build the largest reported library of single-atom catalysts. In conjunction with in situ studies, we uncover unified principles on the oxidation state, coordination number, bond length, coordination element and metal loading of single atoms to guide the design of single-atom catalysts with atomically dispersed atoms anchored on N-doped carbon. We utilize the library to open up complex multimetallic phase spaces for single-atom catalysts and demonstrate that there is no fundamental limit on using single-atom anchor sites as structural units to assemble concentration-complex single-atom catalyst materials with up to 12 different elements. Our work offers a single-atom library spanning from monometallic to concentration-complex multimetallic materials for the rational design of single-atom catalysts. Single-atom catalysts demonstrate enhanced catalytic properties, but most systems only explore combinations of a few different metals. Here, a library of 37 different elements is investigated, and it is shown that loading 12 metallic atoms in one system presents improved electrochemical activity.