Details

Autor(en) / Beteiligte

• Chen, Cheng
• Ou, Wei
• Yam, Kah‐Meng
• Xi, Shibo
• Zhao, Xiaoxu
• Chen, Si
• Li, Jing
• Lyu, Pin
• Ma, Lu
• Du, Yonghua
• Yu, Wei
• Fang, Hanyan
• Yao, Chuanhao
• Hai, Xiao
• Xu, Haomin
• Koh, Ming Joo
• Pennycook, Stephen J.
• Lu, Junling
• Lin, Ming
• Su, Chenliang
• Zhang, Chun
• Lu, Jiong

Titel

Zero‐Valent Palladium Single‐Atoms Catalysts Confined in Black Phosphorus for Efficient Semi‐Hydrogenation

Ist Teil von

• Advanced materials (Weinheim), 2021-09, Vol.33 (35), p.e2008471-n/a

Ort / Verlag

Weinheim: Wiley Subscription Services, Inc

Erscheinungsjahr

2021

Quelle

Wiley Online Library All Journals

Beschreibungen/Notizen

• Single‐atom catalysts (SACs) represent a new frontier in heterogeneous catalysis due to their remarkable catalytic properties and maximized atomic utilization. However, single atoms often bond to the support with polarized electron density and thus exhibit a high valence state, limiting their catalytic scopes in many chemical transformations. Here, it is demonstrated that 2D black phosphorus (BP) acts as giant phosphorus (P) ligand to confine a high density of single atoms (e.g., Pd1, Pt1) via atomic layer deposition. Unlike other 2D materials, BP with relatively low electronegativity and buckled structure favors the strong confinement of robust zero‐valent palladium SACs in the vacancy site. Metallic Pd1/BP SAC shows a highly selective semi‐hydrogenation of phenylacetylene toward styrene, distinct from metallic Pd nanoparticles that facilitate the formation of fully hydrogenated products. Density functional theory calculations reveal that Pd atom forms covalent‐like bonding with adjacent P atoms, wherein H atoms tend to adsorb, aiding the dissociative adsorption of H2. Zero‐valent Pd in the confined space favors a larger energy gain for the synthesis of partially hydrogenated product over the fully hydrogenated one. This work provides a new route toward the synthesis of zero‐valent SACs on BP for organic transformations. Zero‐valent palladium single‐atoms catalysts confined in black phosphorus are successfully synthesized via atomic layer deposition (ALD). This BP‐based SAC with metallic Pd1/P shows a highly selective semi‐hydrogenation of phenylacetylene toward styrene, opening up new avenues for designing zero‐valent SACs on BP for a wide range of organic transformations.