Details

Autor(en) / Beteiligte

• Guo, Jing
• Berbano, Seth S.
• Guo, Hanzheng
• Baker, Amanda L.
• Lanagan, Michael T.
• Randall, Clive A.

Titel

Cold Sintering Process of Composites: Bridging the Processing Temperature Gap of Ceramic and Polymer Materials

Ist Teil von

• Advanced functional materials, 2016-10, Vol.26 (39), p.7115-7121

Ort / Verlag

United States: Blackwell Publishing Ltd

Erscheinungsjahr

2016

Link zum Volltext

Quelle

Wiley Online Library

Beschreibungen/Notizen

• Co‐sintering ceramic and thermoplastic polymer composites in a single step with very high volume fractions of ceramics seems unlikely, given the vast differences in the typical sintering temperatures of ceramics versus polymers. These processing limitations are overcome with the introduction of a new sintering approach, namely “cold sintering process” (CSP). CSP utilizes a transient low temperature solvent, such as water or water with dissolved solutes in stoichiometric ratios consistent with the ceramic composition, to control the dissolution and precipitation of ceramics and effect densification between room temperature and ≈200 °C. Under these conditions, thermoplastic polymers and ceramic materials can be jointly formed into dense composites. Three diphasic composite examples are demonstrated to show the overall diversity of composite material design between organic and inorganic oxides, including the microwave dielectric Li2MoO4–(C2F4 ) n , electrolyte Li1.5Al0.5Ge1.5(PO4)3–(CH2CF2 ) x [CF2CF(CF3)] y , and semiconductor V2O5–poly(3,4‐ethylenedioxythiophene) polystyrene sulfonate composites. Cold sintering is more general and shall have a major impact on the processing of composite materials for many different applications, mechanical, thermal, and electronic, to mention a few possibilities. CSP concepts open up new composite material design and device integration schemes, impacting a wide variety of applications. “Cold sintering process” (CSP) is an extremely low temperature sintering process (between room temperature and ≈200 °C), which makes it promising to co‐sinter ceramic and thermoplastic polymer composites in a simple one‐step sintering processing. CSP concepts open up new composite material design with many different applications, such as electrical and mechanical.