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Zinc‐based Metal Organic Framework Derived From Anthracene and BODIPY Chromophores: Synthesis and Photophysical Properties
Ist Teil von
Bulletin of the Korean Chemical Society, 2021, 42(4), , pp.645-648
Ort / Verlag
Weinheim: Wiley‐VCH Verlag GmbH & Co. KGaA
Erscheinungsjahr
2021
Quelle
Wiley Online Library - AutoHoldings Journals
Beschreibungen/Notizen
Luminescent metal–organic frameworks (MOFs) have emerged as interesting materials due to their excellent photophysical and photochemical properties. Herein, we report the synthesis of a Zn‐based MOF AnDBP MOF derived from anthracenedicarboxylic ligand and dipyridyl boron dipyrromethene (BODIPY) chromophore. The single‐crystal structure of AnDBP MOF showed a noninterpenetrated network structure with zinc metal binding the ligands in an octahedral fashion. The AnBDP MOF showed efficient energy transfer between the linkers and also displayed excellent photocatalytic properties.
A new BODIPY and anthracene based zinc metal–organic framework was synthesized, and its light‐harvesting and photocatalytic properties were described.