Details

Autor(en) / Beteiligte

• Son, Jeong‐Yu
• Baek, Yonghyeon
• Kim, Sanghyuck
• Lee, Kyungsup
• Lee, Phil Ho

Titel

Rhodium(III)‐Catalyzed N−H Insertion Reaction of Phosphoryl Amides with α‐Aryl Diazoesters for the Synthesis of α‐Phosphoryl Amino Esters

Ist Teil von

• Bulletin of the Korean Chemical Society, 2020, 41(6), , pp.615-627

Ort / Verlag

Weinheim: Wiley‐VCH Verlag GmbH & Co. KGaA

Erscheinungsjahr

2020

Quelle

Wiley InterScience Journals

Beschreibungen/Notizen

• An efficient rhodium(III)‐catalyzed N−H insertion reaction is developed from the reaction of phosphoryl amides with α‐aryl diazoesters under aerobic and mild conditions, which produce α‐phosphoryl amino esters in good to excellent yields with high selectivity, a broad substrate scope, and a good functional group tolerance. Also, Rh(III)‐catalyzed N−H insertion reaction of alkenyl phosphonic amides with α‐aryl diazoesters was successful.