Details

Autor(en) / Beteiligte

• Stone, M. E
• Johnson, K. E

Titel

Electronic Spectra of Nickel Chloride in Molten Amides

Ist Teil von

• Canadian journal of chemistry, 1971-12, Vol.49 (23), p.3836-3839

Ort / Verlag

Ottawa, Canada: NRC Research Press

Erscheinungsjahr

1971

Link zum Volltext

Quelle

Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals

Beschreibungen/Notizen

• Solutions of NiCl 2 in molten acetamide and caprolactam have been investigated. The nature of the Ni(II) species present was found to be independent of concentration, over the concentration ranges 0.02 to 0.25 and 0.01 to 0.3 M, respectively; however, it was not independent of temperature. In both solvents, Ni(II) occurred mainly in octahedral environments but an increase in temperature apparently resulted in the formation of tetrahedral species.