Details

Autor(en) / Beteiligte

• Kolesniková, L.
• Kisiel, Z.
• Alonso, E. R.
• Guillemin, J. C.
• Alonso, J. L.
• Medvedev, I. R.
• Winnewisser, M.

Titel

A Comprehensive Spectral Rotational Analysis of the Interstellar Methyl Isocyanate CH3NCO

Ist Teil von

• The Astrophysical journal. Supplement series, 2019-12, Vol.245 (2)

Ort / Verlag

Saskatoon: The American Astronomical Society

Erscheinungsjahr

2019

Quelle

EZB Free E-Journals

Beschreibungen/Notizen

• Methyl isocyanate (CH3NCO) is a recently identified interstellar molecule giving rise to many detected lines. Interestingly, its delayed identification was due not to weak lines but to a very complex rotational spectrum. To date, the only published laboratory transitions for this molecule are those between rotational energy levels with K ≤ 3. In the present work, Stark-modulation spectroscopy was used to record the room-temperature rotational spectrum of CH3NCO in the spectral region from 32 to 90 GHz. Observation of characteristic Stark effects, measured at specific low-voltage modulation conditions, and 14N nuclear quadrupole hyperfine structure allowed unambiguous assignment of rotational transitions up to K = 10. These newly assigned transitions were subsequently followed up to 364 GHz with the aid of Loomis-Wood-type displays. Since there are no reports on astrophysical detection of 13C isotopic species, first laboratory measurements between 50 and 300 GHz have also been performed for CH3N13CO and 13CH3NCO isotopologues. A comprehensive spectral analysis undertaken in this work made it possible to extend the knowledge of the rotational spectrum of CH3NCO to more than 2500 new transitions. Furthermore, more than 1200 lines were identified and analyzed for each of the isotopologues. The extensive line lists and sets of molecular parameters reported in this work provide the basis for further astrophysical searches of CH3NCO.