Details

Autor(en) / Beteiligte

• Kennedy, Chris L
• Sayasilpi, Daphne
• Schall, Peter
• Meijer, Janne-Mieke

Titel

Self-assembly of colloidal cube superstructures with critical Casimir attractions

Ist Teil von

• Journal of physics. Condensed matter, 2022-05, Vol.34 (21), p.214005

Ort / Verlag

England: IOP Publishing

Erscheinungsjahr

2022

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The structure of self-assembled materials is determined by the shape and interactions of the building blocks. Here, we investigate the self-assembly of colloidal 'superballs', i.e. cubes with rounded corners, by temperature-tunable critical Casimir forces to obtain insight into the coupling of a cubic shape and short range attractions. The critical Casimir force is a completely reversible and controllable attraction that arises in a near-critical solvent mixture. Using confocal microscopy and particle tracking, we follow the self-assembly dynamics and structural transition in a quasi-2D system. At low attraction, we observe the formation of small clusters with square symmetry. When the attraction is increased, a transition to a rhombic Λ -lattice is observed. We explain our findings by the change in contact area at faces and corners of the building blocks combined with the increase in attraction strength and range of the critical Casimir force. Our results show that the coupling between the rounded cubic shape and short-range attraction plays a crucial role for the superstructures that form and provide new insights for the active assembly control of micro and nanocubes.