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Calorimetric Investigations of Phase Transitions in KNO3 Embedded Into Porous Glasses
Ist Teil von
Ferroelectrics, 2010-01, Vol.402 (1), p.60-65
Ort / Verlag
Colchester: Taylor & Francis Group
Erscheinungsjahr
2010
Quelle
Taylor & Francis Journals Auto-Holdings Collection
Beschreibungen/Notizen
Results of the Differential Scanning Calorimetry (DSC) studies of porous glasses filled by KNO
3
ferroelectric in wide temperature range are presented. Anomalous heat capacity of the potassium nitrate confined in nanoscale porous glasses with two different radius of pore 23 and 160nm show that the phase I-III transition temperature was slightly affected by particle size, whereas the phase III-II transition temperature significantly decreased. During the heating, the phase II-I transition temperature increased up to 12.5°C comparing to the bulk material. The lowering of the potassium nitrate particle size significantly reduced the phase I-liquid transition temperature.