Details

Autor(en) / Beteiligte

• Krykun, Serhii
• Croué, Vincent
• Alévêque, Olivier
• Levillain, Eric
• Allain, Magali
• Mézière, Cécile
• Carré, Vincent
• Aubriet, Frédéric
• Voïtenko, Zoia
• Goeb, Sébastien
• Sallé, Marc

Titel

A self-assembled tetrathiafulvalene box

Ist Teil von

• Organic Chemistry Frontiers, 2021-03, Vol.8 (5), p.883-890

Ort / Verlag

London: Royal Society of Chemistry

Erscheinungsjahr

2021

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A M 8 L 2 metalla-cage constructed through coordination-driven self-assembly from a quinonato bis-ruthenium complex and an electron-rich tetrathiafulvalene (TTF) tetrapyridyl ligand is depicted. In this molecular box, both TTF units are highly bent and are separated by a distance as short as 3.48 Å in the solid state. This system offers a unique opportunity to study the electronic interactions occurring between two TTF units facing each other in a conformationally rigid environment.