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Controlling disorder in the ZnGa 2 O 4 :Cr 3+ persistent phosphor by Mg 2+ substitution
Ist Teil von
Physical chemistry chemical physics : PCCP, 2017, Vol.19 (2), p.1369-1377
Ort / Verlag
England: Royal Society of Chemistry
Erscheinungsjahr
2017
Link zum Volltext
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
We have studied in this work the effect of increasing structural disorder on the persistent luminescence of a Cr
doped zinc gallate spinel. This disorder was introduced by progressive substitution of Zn
by Mg
ions, and was studied by photoluminescence, X-ray diffraction, extended X-ray absorption fine structure (EXAFS), X-ray absorption near edge structure (XANES) and electron paramagnetic resonance (EPR) spectroscopy. It was found that increasing the Mg/Zn substitution decreases the number of Cr
in undistorted sites and increases the number of Cr
with neighbouring antisite defects and with neighbouring Cr
ions (referred to as Cr clusters), which in turn decreases the intensity of persistent luminescence. Both XANES and EPR spectra could be simulated by a linear combination of Cr
spectra with three types of Cr
environments. The increasing disorder was found to be correlated with a decrease of the average Cr-O bond length and a decrease of crystal field strength experienced by Cr
ions.