Journal of natural products (Washington, D.C.), 1995-10, Vol.58 (10), p.1636-1639
1995
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Details
- Autor(en) / Beteiligte
- Titel
- Structural Revision of Isoeudistomin U by Total Synthesis
- Ist Teil von
- Journal of natural products (Washington, D.C.), 1995-10, Vol.58 (10), p.1636-1639
- Ort / Verlag
- Washington, DC: American Chemical Society
- Erscheinungsjahr
- 1995
- Quelle
- Alma/SFX Local Collection
- Beschreibungen/Notizen
- Pictet-Spengler condensation of indole-3-carboxaldehyde and of tryptamine yielded a tetrahydro- beta -carboline, which was transformed in one step (DDQ-THF) into a compound whose spectral properties were identical with those of isoeudistomin U, a metabolite from a marine tunicate previously assigned an alpha -carboline structure. Eudistomin U [4] was synthesized from "isoeudistomin U" under the same oxidation conditions but with prolonged reaction time and excess of DDQ.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 0163-3864eISSN: 1520-6025DOI: 10.1021/np50124a030Titel-ID: cdi_hal_primary_oai_HAL_hal_02084855v1
- Format
- –
- Schlagworte
- ALDEHIDOS, ALDEHYDE, ALDEHYDES, alpha-carbolines, AMINAS BIOGENICAS, AMINE BIOGENE, Analytical chemistry, ANIMAL PRODUCTS, BIOCHEMICAL PATHWAYS, BIOGENIC AMINES, Biological and medical sciences, BIOSINTESIS, BIOSYNTHESE, BIOSYNTHESIS, CHEMICAL COMPOSITION, CHEMICAL REACTIONS, Chemical Sciences, Chemistry, COMPOSICION QUIMICA, COMPOSITION CHIMIQUE, DERIVATIVES, Exact sciences and technology, General pharmacology, Heterocyclic compounds, Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings, Life Sciences, Lissoclinum fragile, Medical sciences, Medicinal Chemistry, MOLECULAR CONFORMATION, molecular structure, MOLLUSCA, Organic chemistry, Pharmacognosy. Homeopathy. Health food, Pharmacology. Drug treatments, Phytopathology and phytopharmacy, Preparations and properties, PRODUCTOS DE ORIGEN ANIMAL, PRODUIT ANIMAL, REACCIONES QUIMICAS, REACTION CHIMIQUE, TRYPTAMINE, Vegetal Biology, VIA BIOQUIMICA DEL METABOLISMO, VOIE BIOCHIMIQUE DU METABOLISME