Details

Autor(en) / Beteiligte

• Jin, Guanghua
• Werncke, C. Gunnar
• Escudié, Yannick
• Sabo-Etienne, Sylviane
• Bontemps, Sébastien

Titel

Iron-Catalyzed Reduction of CO2 into Methylene: Formation of C–N, C–O, and C–C Bonds

Ist Teil von

• Journal of the American Chemical Society, 2015-08, Vol.137 (30), p.9560-9563

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

2015

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• We report herein the use of the (dihydrido)iron catalyst, Fe­(H)2(dmpe)2, for the selective reduction of CO2 into either bis­(boryl)­acetal or methoxyborane depending on the hydroborane used as a reductant. In a one-pot two-step procedure, the in situ generated bis­(boryl)­acetal was shown to be a reactive and versatile source of methylene to create new C–N but also C–O and C–C bonds.