Details

Autor(en) / Beteiligte

• Cabon, P
• Rumin, R
• Salaün, J. Y
• Triki, S
• des Abbayes, H

Titel

Formation of Anionic Trifunctionalized Metallalactones by Nucleophilic Addition at the β-Carbonyl of a Pyruvoyl Ligand

Ist Teil von

• Organometallics, 2005-03, Vol.24 (7), p.1709-1717

Ort / Verlag

American Chemical Society

Erscheinungsjahr

2005

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Anionic nucleophilic reagents Nu- = CH3O-, C2H5O-, t-BuO-, CH3S-, and P(C6H5)2 - were found to react with (CO)4Fe(CO2CH3)[C(O)C(O)CH3] to afford two isomers of anionic trifunctionalized metallalactones, whose formation resulted from an addition of the nucleophile to the β carbonyl of the pyruvoyl ligand. In this reaction, the metallacycle formation was found to occur by a further addition of the oxygen of the same β carbonyl on a terminal carbonyl. In acidic medium, these anionic complexes evolved into neutral metallalactones already obtained by performing the same reaction with pronucleophiles (Nu-H type reagents). Achievement of when the reaction was performed with t-BuO- could result from an intermediate formation of the enolate form of the pyruvoyl ligand [Fe]C(O)-C(CH2)-O- under basic conditions.