Details

Autor(en) / Beteiligte

• Joost, Maximilian
• Zeineddine, Abdallah
• Estévez, Laura
• Mallet−Ladeira, Sonia
• Miqueu, Karinne
• Amgoune, Abderrahmane
• Bourissou, Didier

Titel

Facile Oxidative Addition of Aryl Iodides to Gold(I) by Ligand Design: Bending Turns on Reactivity

Ist Teil von

• Journal of the American Chemical Society, 2014-10, Vol.136 (42), p.14654-14657

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

2014

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Thanks to rational ligand design, the first gold(I) complexes to undergo oxidative addition of aryl iodides were discovered. The reaction proceeds under mild conditions and is general. The ensuing aryl gold(III) complexes have been characterized by spectroscopic and crystallographic means. DFT calculations indicate that the bending induced by the diphosphine ligand plays a key role in this process.