Details

Autor(en) / Beteiligte

• Ventre, Sandrine
• Simon, Cédric
• Rekhroukh, Feriel
• Malacria, Max
• Amatore, Muriel
• Aubert, Corinne
• Petit, Marc

Titel

Catalytic Version of Enediyne Cobalt-Mediated Cycloaddition and Selective Access to Unusual Bicyclic Trienes

Ist Teil von

• Chemistry : a European journal, 2013-05, Vol.19 (19), p.5830-5835

Ort / Verlag

Weinheim: WILEY-VCH Verlag

Erscheinungsjahr

2013

Quelle

Wiley Online Library

Beschreibungen/Notizen

• Go cyclic! The use of [Co(H)(PMe3)4] as a cobalt catalyst allows the previously unattainable catalytic version of the cobalt‐mediated cycloaddition of enediynes without the requirement of thermal or light activation (see scheme). The importance of a chelating group on the substrate that can selectively direct the reaction pathway toward the classical polycyclic 1,3‐cyclohexadienes or a new family of bicyclic trienes is also demonstrated.