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Lithiated manganese oxide Li0.33MnO2 as an electrode material for lithium batteries
Ist Teil von
Journal of power sources, 2006-09, Vol.159 (2), p.1365-1369
Ort / Verlag
Lausanne: Elsevier Sequoia
Erscheinungsjahr
2006
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
Li0.33MnO2 was prepared by solid-state reaction of CMD oxide and a lithium salt. The structure was studied by X-ray diffraction and Raman scattering during electrochemical discharging. The possibility of application as a positive electrode in rechargeable lithium batteries was investigated. The electrochemical properties of Li//Li0.33MnO2 cells were studied as a function of temperature in the range 25-55 deg C. The electrode material delivers an initial capacity of 194mAhg-1 and shows good reversibility at room temperature. Finally, the lithium insertion mechanism was examined by the determination of the ion kinetics.