Details

Autor(en) / Beteiligte

• Karapetyan, Artak
• Reymers, Anna
• Giorgio, Suzanne
• Fauquet, Carole
• Sajti, Laszlo
• Nitsche, Serge
• Nersesyan, Manuk
• Gevorgyan, Vladimir
• Marine, Wladimir

Titel

Cuprous oxide thin films prepared by thermal oxidation of copper layer. Morphological and optical properties

Ist Teil von

• Journal of luminescence, 2015-03, Vol.159, p.325-332

Ort / Verlag

Elsevier B.V

Erscheinungsjahr

2015

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Structural and optical characterization of crystalline Cu2O thin films obtained by thermal oxidation of Cu films at two different temperatures 800°C and 900°C are investigated in this work. X-ray diffraction measurements indicate that synthesized films consist of single Cu2O phase without any interstitial phase and show a nano-grain structure. Scanning Electron Microscopy observations indicate that the Cu2O films have a micro-scale roughness whereas High Resolution Transmission Electron Microscopy highlights that the nanocrystalline structure is formed by superposition of nearly spherical nanocrystals smaller than 30nm. Photoluminescence spectra of these films exhibit at room temperature two well-resolved emission peaks at 1.34eV due to defects energy levels and at 1.97eV due to phonon-assisted recombination of the 1s orthoexciton in both film series. Emission characteristics depending on the laser power is deeply investigated to determine the origin of recorded emissions. Time-integrated spectra of the 1s orthoexciton emission reveals the presence of oxygen defects below the conduction band edge under non-resonant two-photon excitation using a wide range of excitations wavelengths. Optical absorption coefficients at room temperature are obtained from an accurate analysis of their transmission and reflection spectra, whereas the optical band gap energy is estimated at about 2.11eV. Results obtained are of high relevance especially for potential applications in semiconductor devices such as solar cells, optical sources and detectors. •Nanostructured Cu2O thin films were synthesized by thermal oxidation of Cu films.•The PL spectra of nanostructured thin films revealed two well-resolved emission peaks.•The PL properties were investigated under a broad range of experimental conditions.•Inter-band transition in the infrared range has been associated to VCu and VO vacancies.•Absorption coefficients and the band gap energy were estimated from the R and T data.