Angewandte Chemie (International ed.), 2004-07, Vol.43 (28), p.3728-3731
2004
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Details
- Autor(en) / Beteiligte
- Titel
- Thermally Induced Electron Transfer in a CsCoFe Prussian Blue Derivative: The Specific Role of the Alkali-Metal Ion
- Ist Teil von
- Angewandte Chemie (International ed.), 2004-07, Vol.43 (28), p.3728-3731
- Ort / Verlag
- Weinheim: WILEY-VCH Verlag
- Erscheinungsjahr
- 2004
- Quelle
- Alma/SFX Local Collection
- Beschreibungen/Notizen
- A central role for the alkali metal cation was determined in the thermally activated electron transfer CoIII(LS)‐FeII(LS) ⇌CoII(HS)‐FeIII(LS) in a CsCoFe Prussian blue derivative by localizing the alkali metal ion and identifying its interactions with the surrounding network in the high‐ and low‐temperature states (see scheme).
- Sprache
- Englisch
- Identifikatoren
- ISSN: 1433-7851eISSN: 1521-3773DOI: 10.1002/anie.200460086Titel-ID: cdi_hal_primary_oai_HAL_hal_00087524v1
- Format
- –
- Schlagworte
- electron transfer, Prussian blue analogues, spin crossover, X-ray absorption spectroscopy, X-ray diffraction