Details

Autor(en) / Beteiligte

• Sasaki, Isabelle
• Mallet-Ladeira, Sonia

Titel

Two Different Compounds in One Crystal: di-[mu]-chlorobis[2

Ist Teil von

• Journal of chemical crystallography, 2023-06, Vol.53 (2), p.293

Ort / Verlag

Springer

Erscheinungsjahr

2023

Quelle

SpringerLink

Beschreibungen/Notizen

• The crystal structures of di-[mu]-chlorobis[2-(5-methyl-pyridin-2-yl-[kappa]N)phenyl-[kappa]C(1)] diplatinum(II) (1) and chloro(N,N-dimethylformamide-[kappa]O)[2-(5-methyl-pyridin-2-yl-[kappa]N)phenyl-[kappa]C(1)]platinum(II) (2) have been determined by means of the X-ray diffraction. Both complexes cocrystallize in the monoclinic space group C2/c with a = 39.5457(18) Å, b = 7.2482(4) Å, c = 21.2269(10) Å and [beta] = 121.460(2)°. The asymmetric unit consists of half a centrosymmetric compound (complex 1) and one full independent compound (complex 2). Graphical The X-ray structures of co-crystallized di-[mu]-chlorobis[2-(5-methyl-pyridin-2-yl-[kappa]N)phenyl-[kappa]C(1)]diplatinum(II) (1) as starting material and of the derivative chloro(N,N-dimethylformamide-[kappa]O)[2-(5-methyl-pyridin-2-yl-[kappa]N)phenyl-[kappa]C(1)]platinum(II) (2) are reported.