Journal of radioanalytical and nuclear chemistry, 2020-12, Vol.326 (3), p.1727-1732
2020
Volltextzugriff (PDF)
Details
- Autor(en) / Beteiligte
- Titel
- Terminal alkyne semi-tritiation with Lindlar catalyst and its mechanism implications
- Ist Teil von
- Journal of radioanalytical and nuclear chemistry, 2020-12, Vol.326 (3), p.1727-1732
- Ort / Verlag
- Cham: Springer International Publishing
- Erscheinungsjahr
- 2020
- Quelle
- Alma/SFX Local Collection
- Beschreibungen/Notizen
- It has been nearly 70 years since the discovery of Lindlar catalyst and its valuable ability to semi-hydrogenate alkynes to cis olefins. The Lindlar catalyst semi-hydrogenation mechanism appears to still be an ongoing discussion. Spectroscopy (NMR, MS) results are presented regarding the Lindlar catalyst semi-tritiation of terminal alkynes, providing evidence of a novel tritium for hydrogen exchange process taking place.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 0236-5731eISSN: 1588-2780DOI: 10.1007/s10967-020-07468-zTitel-ID: cdi_gale_infotracacademiconefile_A651092411
- Format
- –
- Schlagworte
- Calcium carbonate, Chemical tests and reagents, Chemistry, Chemistry and Materials Science, Diagnostic Radiology, Hadrons, Heavy Ions, Hydrogen, Hydrogenation, Inorganic Chemistry, Nuclear Chemistry, Nuclear magnetic resonance spectroscopy, Nuclear Physics, Olefins, Palladium, Palladium catalysts, Physical Chemistry, Quinoline